• 专利附录
  • 专利说明
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    • 专利摘要:
    food packaging and combination film the image printed on a main face of a flexible food packaging film is covered by a shellac barrier coating
    公开号:BR112012003769B1
    申请号:R112012003769
    申请日:2010-08-26
    公开日:2019-12-10
    发明作者:Zhong Bin；C Battersby Graham；A Santos Stephen；Gan Xiangdong
    申请人:Mantrose Haeuser Company Inc；
    IPC主号:
    专利说明:

    FOOD PACKAGE FILM
    Cross Reference for Related Orders [0001] Priority is claimed for North American provisional order No. 61/236, 907, filed on August 29, 2009, the disclosure of which is hereby incorporated by reference.
    Background of the Invention [0002] This invention relates to food packaging materials in the form of flexible films having printed images.
    [0003] In order to provide food packaging films with improved barrier properties, multi-layer films of two or more synthetic resins are commonly used. Examples include laminated polyethylene / polypropylene ("coex") for polyethylene terephthalate (PET), laminated PET for LDPE (low density polyethylene), and laminated metallized PET for coex. Other such multi-layered food packaging films can be formed from nylon, foil, and ethylene vinyl acetate polymers and copolymers.
    [0004] Where it is desired to provide such laminated packaging films with the printed images, the image is usually printed on the outside of the film, that is, on the main face of the film not facing the food in the packaging. When transparent or translucent packaging films are used, the image can be printed inside the film.
    [0005] To protect these printed images from damage due to friction, bending, abrasion and heat sealing, these printed images are often covered with a suitable coating to make a barrier or "print trap film." See, U.S. Patent No. 7,063,882 to Mossbrook et al. , the full description of which is incorporated herein by reference. If so, these print trap films are usually made of materials suitable for direct contact with food ("food compatible material"), even if the image is printed on the outer face of the packaging film. Because most packaging films are supplied in the form of large rolls, films with printing traps on the outer face of a film contact the inner face of the film when the film is wound on itself to form the roll. Therefore, even if the packaging film is printed on its outer face, the film with the printing trap will normally be made of a food-compatible material to avoid contamination of the inner face of food contact of the same film.
    [0006] Printed films can be applied to printed packaging films by any conventional technique. For example, printing films can be applied by extrusion coating, if desired. However, due to the time required to set up the extruder and the considerable waste generated when the extruder is started and stopped, extrusion coating generally requires long production cycles to be economically viable.
    [0007] Films with printing can also be applied by laminating with adhesive bonding. However, this approach limits the inks that can be used for printing to those that maintain very low levels of solvent so as not to adversely affect the bond strength of the subsequently applied adhesive. These adhesives generally exhibit low bond strength before curing, which can result in unwanted blistering and / or "encapsulation." In addition, complete curing of these adhesives can be slow, which often requires these films to be stored before processing is complete, which in turn increases capital costs. In situations where two component adhesives are used, these adhesives must be discarded if they are not applied quickly enough, which also increases costs.
    [0008] In order to avoid these problems, it has also been proposed to form such printing films from activated electron beam coatings. However, the choice of beam curing equipment is not widely available in the food packaging industry. Additionally, this equipment, as well as the materials used in the beam's coating electrons, in general, are expensive.
    Summary [0009] In accordance with the present invention, these problems are avoided by forming such shellac or similar printing films.
    [0010] Thus, the present invention provides a food packaging film comprising a flexible film substrate made of a material that exhibits better resistance to penetration by water vapor and oxygen than paper, the flexible film substrate having a pair of larger opposing faces, an image printed on at least one larger face, and a barrier coating covering the printed image, the barrier coating comprising an impermeable water vapor, of biological origin, and food-compatible film-forming material .
    [0011] A packaged food product comprising a food product packaged by such food packaging film is also provided.
    DETAILED DESCRIPTION OF THE INVENTION
    Flexible film substrate [0012] Essentially, any material that has been used previously, or will be used in the future, to form a flexible food packaging film with improved barrier properties can be used as the flexible film substrate of the present invention. In this context, "food" will be understood to include liquids and semi-solids such as pudding and gelatin, as well as traditional solid foods. In addition, the term "improved barrier properties" will be understood to mean that the material used to form the substrate has a better resistance to penetration by oxygen and water vapor than paper. Thus, the substrate of the food packaging film of the invention can be made from a wide variety of different synthetic resins such as polyethylene (LDPE, LLPE, VLDPE, HDPE, MDPE), polypropylene, polyethylene terephthalate, nylon, other polymers and vinyl copolymers, such as those made from vinyl acetate, vinyl alcohol, vinyl chloride, etc., and so on. In addition, the substrate of the food packaging film of the invention can also be made from metal sheets, such as aluminum foil and the like. Additionally, the inventive food packaging film substrate can also be made from a wide variety of different naturally occurring films forming resins, especially those that are degradable, biodegradable or compostable.
    [0013] A degradable resin is a resin that undergoes significant changes in its chemical structure under specific environmental conditions, resulting in the loss of some properties. A biodegradable resin is a degradable resin that degrades from naturally occurring microorganisms, such as bacteria, fungi, etc. A compostable resin is a biodegradable resin that biodegrades over a period of time similar to that of cellulose in a decomposition product, which is both non-toxic and disintegrated.
    [0014] Biodegradable resins are typically derived from renewable raw materials, such as starch (eg, corn, potatoes, tapioca, etc.), cellulose, soy protein, lactic acid, etc. They are not dangerous in production and usually decompose back to carbon dioxide, water, biomass, etc. when discarded. Corn starch is currently the main raw material to be used in the production of bioplastic resins. Mater-Bi (Main component of corn starch), and polylactides (PLA) (made from corn starch) are currently the two main resins (raw materials), being used today in the production of compostable and biodegradable resins and are certified for compostability according to standards established by international organizations. However, other bioplastics entering the market are made from potato starch, soy protein, cellulose, etc. Currently, most of these bioplastics are not certified for composting, although some are for biodegradability. The bioplastics field is constantly evolving with new materials and technologies that are being worked on and are being brought to the market.
    [0015] Preferred biodegradable resins ("bioplastics") are those that are not only biodegradable, but also compostable. Especially preferred bioplastics are in accordance with the ASTM-6400 standard, referring to compostable plastics. As described here, a Compostable Plastic in accordance with this standard is one that is "capable of undergoing biological decomposition at a site of the compound as part of an available program, such that the resin is not visually distinguishable and breaks down into dioxide of carbon, water, inorganic compounds, and biomass, at a rate consistent with known compostable materials (eg cellulose) and leaves no toxic residue. " [0016] According to the ASTM-6400 standard, a resin is compostable if it exhibits certain minimum levels of biodegradability, ability to disintegrate and non-toxicity. A resin is biodegradable under this standard, if at least 60% of the resin is biodegraded within 180 days, as measured by the amount of CO2 produced by this decomposition. A resin is disintegrable according to this standard if less than 10% of its decomposition product, when sieved, remains on a 2 mm screen. A resin is non-toxic under this standard, if the heavy metal content of its decomposition product remains below certain prescribed limits and, in addition, if when combined with the soil, in different concentrations, it is able to withstand a certain level of plant growth in relation to a control compound.
    [0017] Compostable resins, as well as packaging and other products made from them, are described in a number of recently published and / or filed patent documents, examples of which include: US 7,083,673, US 2008/0153940, US 2008/0113887, US 2007/0259139, US 2007/0203283, US 2007/0148384, US 2007/0127067, US 2004/0217087, US2005 / 0192377, US 2005/0039689, US 2004/0059047, US 2003/0236358, US 2003/0204028, US2003 / 0204027 and US 2003/0191210. Disclosures in these documents are hereby incorporated by reference.
    [0018] As indicated above, many biodegradable and / or compostable resins and products are already known and commercially available. Examples include products made from 100% cane sugar fiber (bagasse), products made from corn plastics (which are polylactides or "PLA"), and products made from potato starch and / or starch of corn. Specific commercially available products include Earthshell® from the disposable product line available from Earthshell Corporation of Lutherville, Maryland, the line of compostable food and beverage containers currently being introduced by New Ice, Inc. of Durango, Colorado, and the line NatureFlexTM packaging films available from Innovia Films in Merelbeke, Belgium.
    [0019] As indicated above, any of these materials can be used to form the substrate of the food packaging film of the invention. In some embodiments of the present invention, combinations of two or more of these materials can also be used for this purpose. For example, mixtures of two or more of these materials can be used to form a single layer film, or even a multilayer film. Most commonly, however, the substrate of the food packaging film of the invention will be formed from a multi-layer film composed of two or more layers of the materials connected above by any known technique, such as co-extrusion, lamination with or without an adhesive, coating, etc. For example, any of the multi-layer products described in the background section of the present disclosure can be used for this purpose, in particular laminated coextruded polyethylene / polypropylene ("coex") to polyethylene terephthalate (PET), PET laminated to LDPE ( low density polyethylene), and laminated metallized PET for coex.
    [0020] In these embodiments of the present invention in which the printed image is located on the largest internal face of the substrate, this substrate will normally be formed from an image-transparent film. In this context, "transparent image" refers to a film that is sufficiently translucent so that an image printed on the main inner face of the film can be discerned when viewed from outside (or another) of the main face of the film. In other words, the image can be seen through the film. Thus, it will be understood that the flexible transparent image film substrate can be made, not only from transparent materials, but also from materials that are translucent, provided that the film substrate is thin enough for the image printed on its main inner face can be discerned when viewed through its large outer face.
    [0021] The thickness of the flexible film substrate of the food packaging film of the invention is not critical and essentially any thickness can be used. However, the film substrate must be thin enough so that the food packaging film of the feed made therefrom remains flexible enough to serve as a food packaging wrapper still thick enough to provide the necessary structural integrity and barrier properties. for the intended application. In this context, "packaging wrapper" will be understood as referring to a film of material that resembles a conventional aluminum foil and / or plastic film in terms of its flexibility in the sense that it can be supplied in the form of a continuous sheet rolled up on itself, then unrolled from the roll, and then easily used to wrap different foods by hand. Thus, a "packaging wrapper" will be understood to include, for example, plastic bags and other relatively flexible plastic packaging materials, but excluding the more rigid materials. For example, although a Styrofoam cup can be considered as "flexible", it is not considered as a "packaging wrapper" in the context of the present disclosure, because it is not flexible enough to be rolled up on itself or to easily fold over itself. even when wrapping different foods by hand.
    [0022] Typically, this means that the flexible film substrate will be at least about 1 micron thick. Minimum thicknesses of at least about 10 microns, at least about 50 microns, or even at least about 100 microns or even at least about 150 microns are more interesting. In terms of maximum thickness, this usually means that the flexible film substrate will not be greater than about 5,000 microns in thickness. Maximum thicknesses of no more than about 1,000 microns, no more than about 500 microns, or even no more than about 250 microns are more interesting.
    [0023] As appreciated by those skilled in the art, minimum, maximum, and desired thicknesses depend, at least in part, on the material in particular of the flexible film substrate that is made from it, as well as its intended utility, and can be easily determined by routine experimentation.
    Printed image [0024] As indicated above, the printed image of the food packaging film of the invention can be applied to both main faces of the film substrate, that is, on its main interior or on its main external face. In addition, the same or different printed images can be applied to both main faces of the substrate, if desired. For this purpose, any known printing technique can be used, including engraving printing, inkjet printing, silk screen printing, flexographic printing, lithographic printing, electrophotographic printing, embossed printing, buffer printing, pad printing , printing of printed letter, etc.
    [0025] Any printing ink that has been used previously, or that can be used in the future, for printing images on flexible food packaging films can also be used to form the printed images of the food packaging film of the invention. A particular advantage of the present invention is that the shellac and analog barrier coatings provided by this invention effectively prevent contact between this ink and the food product to be packaged. As a result, printing inks that are not suitable for food contact can be used in the present invention, as well as those that are suitable for food-grade contact, because these barrier coatings effectively isolate used ink from food that is being shaped.
    [0026] Examples of printing inks suitable for use in the present invention include solvent-based inks, such as modified nitrocellulose inks, polyurethane inks, polyvinyl chloride-based inks, polyamide-based inks, and inks based on polyvinyl butyral; water based inks such as acrylic polymer based inks, polymer resin based inks, protein based printing inks and modified acrylics; and 100% solid inks, such as acrylate inks cured with ultraviolet light (UV), cationic inks cured with UV, inks cured with electron beam (EB), and non-acrylate inks cured by UV.
    [0027] These printing inks can be used to form any type of printed image on one or both main faces of the flexible substrate film of the flexible food packaging film of the invention. For example, purely fanciful designs and art can be printed, as well as images and / or evidence providing useful information, such as, for example, images of food items to be packaged, size, volume, quality, and / or brand of items. food products being packaged, and the like. Printed images, printed on the larger inner face of the substrate, of course, require the need to be the reverse of the image to be viewed by the reader, since it will see through the substrate from its outer face.
    Barrier coating [0028] According to the present invention, the printed image appearing on a main face of the film substrate of the flexible food packaging film of the invention is coated with a barrier coating made from shellac or other analogous material. Because these films can be easily applied by simple coating techniques, the work and expense associated with extrusion coating and electron beam coating techniques are completely avoided. In addition, because shellac and its analogs are essentially non-reactive with printing inks (and solvents) normally used for printing flexible food packaging films, the problem and expense associated with laminating adhesive techniques are also avoided . At the same time, shellac and its analogs exhibit excellent barrier properties that can be used to complement the barrier properties of flexible film substrates on which they are applied. The overall result is that flexible food packaging films that exhibit excellent barrier properties can be produced very simply and cheaply.
    [0029] Shellac coatings have been used for many years as food preservatives. For example, apples and other fruits, both whole and in sections, are commonly coated with shellac to prevent degradation of moisture and atmospheric oxygen. In accordance with the present invention, shellac or the like is used as a barrier coating on the printed image formed on a main face of the substrate of the flexible food packaging film of the invention, not only to protect the food to be packaged from contact with the printing ink from which the image is made, but also to improve the barrier properties of the film of the invention for food packaging as a whole.
    [0030] Shellac is a thermoplastic naturally obtained from secretions of the female lacquer insect. It exhibits a remarkable combination of properties making it an ideal food packaging material, these properties, including low oxygen permeability, water vapor, CO2, ethylene and various odors, low lipid solubility, excellent color and excellent clarity. It is also food compatible, has a very low odor, and does not impart aromas, smells or flavors to packaged foods.
    [0031] Shellac is commercially available in four different classes, orange shellac, de-waxed orange shellac, regular bleached shellac ("white wax shellac" in Europe) and refined bleached shellac. Any type of shellac is useful for carrying out this invention. Dewaxed orange shellac is preferred, while refined bleached shellac is even more preferred.
    [0032] Instead of and / or in addition to shellac, any other film-forming material of biological origin, impervious to water vapor, compatible with food, can also be used. In this context, "organic origin" means material of animal or vegetable origin, as opposed to material derived from mineral coal, oil, natural gas, oil sands or similar hydrocarbon material. In addition, "compatible food" means that the material is suitable for contact with food and / or drinks, as determined by the US Code of Federal Regulations. In addition, "water vapor impermeable" means that the material's resistance to water vapor permeation at room temperature is at least 50% of the refined bleached shellac. In some embodiments of the present invention, the shellac analogue will have a resistance to water vapor permeation at room temperature of at least 75%, 85% or even 95% of refined shellac bleach, while in other forms In the embodiment, the shellac analogue will have a resistance to water vapor permeation at room temperature at least as good as that of refined bleached shellac.
    [0033] Preferably, these film-forming shellac analogs also have low oxygen permeability. By "low oxygen permeability" it means that the oxygen impermeability of the material is at least 50% of the refined bleached shellac, as determined by the time it takes to open an apple cut section coated with the material to develop a brown color noticeable through oxidation. Preferred shellac analogs have oxygen impermeability of at least 75%, or even 85%, 95% or 100% of refined bleached shellac.
    [0034] It is also desirable that these shellac analogs are insoluble in the lipid, as they can prevent the packaging film of the invention from losing its transparency when it comes in contact with lipids or other organic liquids. By "insoluble lipid" is meant that the amount of a 1 gram sample of the material that dissolves in canola oil, at room temperature after 24 hours, is less than twice that of the refined bleached shellac. Analogs of shellac with solubilities in canola oil less than 1.5 times that of refined bleached shellac are more interesting, while those that have solubilities in canola oil less than that of refined bleached shellac are even more interesting.
    [0035] Any film-forming material of organic origin, compatible with food, impermeable to water vapor, exhibiting the above properties can be used as the analogue of shellac in the present invention. Thus, suitable shellac analogs can be selected from certain polysaccharides including cellulose and its derivatives, such as hydroxyethyl cellulose (HEC), ethyl cellulose and microcrystalline cellulose. Suitable shellac analogs can also be selected from lipids and resins including waxes and oils, such as paraffin wax, carnauba wax, beeswax, candelilla wax and polyethylene wax; fatty acids and monoglycerides, such as stearyl alcohol, stearic acid, palmitic acid, mono- and di-glycerides; naturally occurring, such as wood resins, and coumarone-indene resin. Suitable shellac analogs can also be selected from proteins, including corn zein (a-zein, b-zein and / or v-zein), wheat gluten, soy protein, peanut protein, keratin, collagen, gelatin, milk protein (casein) and whey protein. In addition, the protective coatings described in published patent application US 2007 / 02,922,643, the full disclosure of which is incorporated herein by reference, can also be used. Examples include Chitosan-NaOH, ethyl cellulose, Curdlan, Konjac deacetylated, Michelman VaporCoat® 2200R, NuCoat® 6661B, etc. Mixtures of these materials can also be used.
    [0036] The properties exhibited by films made from shellac analogs depend not only on the material itself, including characteristics such as molecular weight and purity, but also on other parameters, such as any other material that may also be present , coating thickness, and the manner in which the film is applied. Thus, care must be taken in the selection of specific materials for use as shellac analogs to select the materials and / or combinations of materials that allow reaching the level of impermeability to water vapor and other desired properties, taking into account these variables . Based on these considerations, technical persons in the art will have no difficulty in choosing particular film-forming materials for particular applications.
    [0037] In addition to these naturally occurring film-makers, the barrier coatings of the present invention can also be formulated with other additional ingredients. For example, these barrier coatings may include film-forming materials of organic origin that do not have the water vapor resistance properties above. Examples include certain types of polysaccharides such as carboxymethyl cellulose (CMC), methyl cellulose (MC), hydroxypropyl cellulose (HPC) and hydroxypropyl methyl cellulose (HPMC); starches and derivatives, such as crude starch, modified starch, pregelatinized starch, dextrin, corn syrup sucrose, maltodextrin, dextrose / fructose and sugar polyols; extruded gums, such as gum arabic, ghatti gum, karaya gum and tragacanth gum; seed gums, such as guar gum and locust bean gum; microbial fermentation gums, such as xanthan, Gallan gum and chilosan; algae extracts such as agar, alginates, carrageenans and furcellaran; and pectins.
    [0038] Still additional ingredients that can be included in the barrier coatings of the present invention include plasticizers, "detackifiers" and coloring agents. Examples of suitable plasticizers include glycols such as polyethylene glycol (PEG), polypropylene glycol (PPG), etc., lipids, such as vegetable oils, mineral oils, medium chain triglycerides, fats, fatty acids, waxes, etc. Examples of suitable detackifiers include proteins, such as zein, etc., and lipids such as acetylated monoglycerides, medium chain triglycerides, oils, waxes, fatty acids such as stearic acid and oleic acid, etc. Examples of suitable coloring agents include pigments such as organic pigments and inorganic pigments, dyes and other naturally occurring dyes.
    [0039] The barrier coatings of the present invention can be applied to the flexible substrate film by any conventional technique. Generally, the ingredients that form the protective coating of the invention will be combined with a suitable liquid carrier to form a liquid coating composition and the composition thus formed, then applied to the flexible film substrate by any suitable means, such as brushing, spraying , immersion or the like. Examples of suitable carrier liquids include water, various alcohols, such as methanol, ethanol, isopropanol, etc. different ketones, such as acetone, methyl ethyl ketone, etc., various glycols, such as propylene glycol, etc., various glycol ethers, various esters such as ethyl acetate, and so on. A particular advantage of using organic solvents based on liquid vehicles is that application speeds are generally high since organic solvents tend to evaporate more quickly than water. On the other hand, a particular advantage of using liquid water-based vehicles is that the discharge of organic solvents into the atmosphere is largely eliminated.
    [0040] The thickness of the barrier coatings of the present invention can vary widely and, essentially, any thickness that will provide the desired degree of protection can be used. Generally speaking, thicknesses of the order of at least about 0.1 microns, more typically at least about 1 micron, or even at least about 5 microns are contemplated, as well as maximum thicknesses not exceeding about 100 microns, more typically no larger than about 50 microns, or even no more than about 10 microns. Typically, the coating compositions used to form the barrier coatings of the present invention will be formulated so that they can be applied in a single application, although several applications can be used, if desired. In this context, a particular advantage of using multiple applications is that it eliminates or at least substantially reduces the adverse effects of defects and / or pin holes that can form in the barrier coating if a single application is used.
    [0041] The proportions of ingredients in the barrier coatings of the present invention can also vary widely and essentially any amounts can be used. Typically, these coatings will contain at least about 50% by weight of shellac or the like based on the combined weight of the protective coating, i.e. excluding any liquid vehicle used to apply the coating. Most commonly, these protective coatings will contain about 65, 75, 85 or even 95% or more by weight of shellac or the like.
    [0042] Similarly, the barrier coatings of the present invention can also contain up to about 40% by weight of film co-former on the same basis (i.e., excluding any liquid carrier), although the amounts of film co-formers in the order up to about 30% by weight, 20% by weight or even 10% by weight are more common. If used, the film co-former will normally be present in an amount sufficient to achieve a noticeable change in the properties of the barrier coating generally of at least about 0.5% by weight, 1% by weight, 2% by weight or even 5% by weight on the same basis.
    [0043] The barrier coatings of the present invention can also contain about 0-50% by weight of detackifier on the same basis, although detackifier concentrations in the order of> 0 to 40% by weight, about 3 to 35% by weight or even about 535% by weight are more common, at least when shellac is selected as the primary film-forming resin. Similarly, the barrier coatings of the present invention can also contain about 0-50% by weight of plasticizer on the same basis, although plasticizer concentrations in the range of> 0 to 40% by weight, about 3 to 35% by weight or even about 5 -35% by weight are more common.
    [0044] The barrier coatings of the present invention can be transparent or colored. If colored, the amount of coloring agent used should be sufficient to develop the desired color. In this regard, a particularly interesting feature of the present invention is that with the barrier coatings of the present invention they can be provided with a contrasting color that forms the printed image on the substrate coating. In this context, "contrasting color" means a color that makes the image printed on the flexible substrate film more easily visible, compared to an otherwise identical barrier film in which no dye is used. Thus, dye concentrations on the order of about 0.1 to 3% by weight, more commonly about 0.3 to 2% by weight, or even 0.4 to 1% by weight for very light colors or tones are contemplated, while dye concentrations in the range of 10-30% by weight for organic pigments and 40-60% by weight for inorganic pigments such as titanium dioxide are contemplated.
    [0045] In addition to the above ingredients, the barrier coatings of the present invention can also be supplied with yet other materials desired to provide functional characteristics. For example, barrier coatings can be composed of materials that provide the coatings with heat resistance, a desired friction coefficient, blocking resistance, bend resistance, glossy or matte appearance, antibacterial or antifungal properties, branded protection materials , interesting optical effects, such as those obtained from nacreous pigments or light interference pigments, metallic pigments, fragrances, including those fragrances incorporated in encapsulated materials that can be released over time, or when the capsule is fractured, and similar.
    [0046] The concentration of the liquid carrier used to form the coating compositions used to form the barrier coatings of the present invention can also vary widely, and essentially any amount can be used. Liquid vehicle concentrations in the range of about 20 to 90% by weight or more are possible, based on the total weight of the coating composition as a whole, although concentrations in the range of 40 to 85% by weight, 55 to 75% in weight are more common.
    [0047] According to another embodiment of the present invention, the barrier coatings of the present invention are the applied pattern, that is, they are applied in a predetermined pattern, then covering less than the total surface area the main inner face of the flexible film substrate. With this approach, a suitable barrier can be provided in selected areas of the invention film for food packaging, such as those areas where greater protection against contact between the printing ink and the food to be packaged is required. Additionally or alternatively, the barrier coating can be made in a different color from both the flexible film substrate and the image printed on it, so that the barrier coating generates its own complementary graphic thus creating a multiple image / design of the graphic with the printing ink.
    [0048] A particular advantage of the present invention, at least when shellac or other similar organic material is used to form the barrier coating, is that these materials are derived from renewable and sustainable resources. In addition, if the flexible film substrate used to form the packaging material of the invention is biodegradable, an additional benefit of the invention is that this entire packaging film is biodegradable, which is a significant advantage when the packaging film of the invention is eliminated by via landfill.
    [0049] Yet another advantage of this invention is that the barrier coatings of the present invention, at least when formed from shellac, can be easily removed by dissolving in alcohol or other similar solvent. This is particularly advantageous in situations where it is desired to recycle the packaging material of the invention to recover and reuse the material from which its flexible film substrate is made.
    [0050] In this regard, many laminates cannot be effectively recycled or disposed of, except in landfills because they contain incompatible materials. For example, a laminated paper and LDPE compound will not biodegrade and therefore is not compostable. Nor can LDPE or paper layers be recovered and recycled separately, because they are an integral part of the laminate. Likewise, a PET / Al-foil / LDPE laminate cannot be recycled and can only be disposed of in a landfill, because all of its layers are not biodegradable and cannot be separated from one another.
    [0051] This problem is avoided by the packaging film of the invention, because the barrier coating can be readily removed by establishing bleaching processes such as aqueous washing or flotation bleaching processes used for bleaching and recycling printed paper. In addition, because the barrier coating of the packaging film of the invention is made from a film-forming material of organic origin, compatible with food, it can be used directly as a food for the recycling processes of polymers that form agglomerates. of thermoforming polymer from lower grade recycled polymers. Such low grade recycled polymers are used to make a wide variety of different products, for example, garden furniture, by molding thermoplastic polymer pellets produced from these recycled polymers. Laminated structures formed from metal sheets and / or thermosetting plastics are not suitable for this purpose, as these materials cannot be recycled or thermoformed. This problem is avoided by the packaging film of the invention, at least when its flexible film substrate is made from a thermoplastic material, because the amalgamated material produced by combining its substrate and coating together is still thermoformable.
    EXAMPLES
    [0052] The following tables illustrate hypothetical coating compositions that can be used to form the barrier coatings according to the present invention: Table 1 Coating composition for basic performance Oxygen impermeable, water insoluble barrier coating, insoluble in lipid.
    Table 2 Composition of coating for plasticized and detackified rendering Oxygen-impermeable barrier coating, insoluble in water, insoluble in lipid [0053] Although only a few embodiments of the present invention have been described above, it will be appreciated that many modifications can be made without depart from the scope and scope of the invention. All such modifications are intended to be included within the scope of the present invention, which is to be limited only by the following claims: CLAIMS
    权利要求:
    Claims (12)
    [1]
    1. Food packaging film characterized by having sufficient flexibility so that it can be supplied in the form of a continuous sheet rolled over itself and then unwound from the hand wrapping roll, in which the film Food packaging comprises a flexible film substrate made of a material that shows better resistance to the penetration of oxygen and water vapor than paper, selected from the group consisting of synthetic resins, metal sheets and resins forming naturally occurring film which are at least one of degradable, biodegradable and compostable, wherein the flexible film substrate having a pair of opposite main faces, and comprising an image printed on at least one of the main faces, and a barrier coating covering the printed image, the barrier coating comprising a film-forming material impermeable to water vapor, of organic origin and compatible with food having a resistance to water vapor permeation at room temperature that is at least 50% that of refined bleached shellac and an oxygen impermeability of at least 50% that of refined bleached shellac.
    [2]
    2. Food packaging film according to claim 1, characterized in that the barrier coating comprises shellac.
    [3]
    Food packaging film according to claim 2, characterized by the fact that the barrier coating comprises at least one of dewaxed orange shellac and refined bleached shellac.
    [4]
    Food packaging film according to any one of claims 1 to 3, characterized in that the barrier coating includes a film co-former.
    [5]
    5. Food packaging film according to any one of claims 1 to 4, characterized by the fact that the substrate is a multilayer article and also by the fact that at least two of the layers in this multilayer article are different from each other .
    [6]
    Food packaging film according to any one of claims 1 to 5, characterized in that the substrate is formed from a synthetic resin, a naturally occurring resin or a combination thereof.
    [7]
    7. Food packaging film according to any one of claims 1 to 6, characterized in that the barrier coating has a resistance to water vapor permeation at room temperature of at least 75% of that of shellac refined bleached and an oxygen impermeability of at least 75% that of refined bleached shellac.
    [8]
    Food packaging film according to any one of claims 1 to 7, characterized in that the barrier coating is insoluble in lipids.
    [9]
    Food packaging film according to any one of claims 1 to 8, characterized by the fact that the flexible film substrate is biodegradable and also by the fact that the barrier coating comprises shellac.
    [10]
    10. Food packaging film according to claim 9, characterized in that the flexible film substrate is compostable.
    [11]
    Food packaging film according to any one of claims 1 to 10, characterized in that the flexible film substrate is made from laminated co-extruded polyethylene / polypropylene for polyethylene terephthalate, laminated polyethylene terephthalate for polyethylene of low density or laminated metallized polyethylene terephthalate for coextruded polyethylene / polypropylene.
    [12]
    Food packaging film according to any one of claims 1 to 5 and 7 to 10, characterized in that the flexible film substrate is made from a multilayer film in which at least one of the layers is selected from from the group consisting of nylon, sheet metal and ethylene vinyl acetate polymers and copolymers.
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    同族专利:
    公开号 | 公开日
    JP2020001830A|2020-01-09|
    CN102548753A|2012-07-04|
    JP2015037971A|2015-02-26|
    WO2011025858A1|2011-03-03|
    TR201820321T4|2019-01-21|
    IL218275A|2016-10-31|
    MX2012002228A|2012-08-15|
    JP2017206316A|2017-11-24|
    EP2470365A4|2014-07-09|
    AU2010286690A1|2012-03-08|
    BR112012003769A2|2016-04-12|
    AU2010286690B2|2014-08-21|
    SG178882A1|2012-04-27|
    CA2772305C|2017-01-03|
    KR101738554B1|2017-06-08|
    CA2772305A1|2011-03-03|
    IL218275D0|2012-04-30|
    JP2013503089A|2013-01-31|
    KR20120050496A|2012-05-18|
    PL2470365T3|2019-05-31|
    NZ598281A|2015-12-24|
    US20120207887A1|2012-08-16|
    CN102548753B|2016-01-20|
    EP2470365A1|2012-07-04|
    EP2470365B1|2018-10-17|
    HK1171718A1|2013-04-05|
    ES2705211T3|2019-03-22|
    US9102125B2|2015-08-11|
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    法律状态:
    2018-04-10| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
    2019-02-12| B06T| Formal requirements before examination [chapter 6.20 patent gazette]|
    2019-07-02| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2019-10-22| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2019-12-10| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/08/2010, OBSERVADAS AS CONDICOES LEGAIS. (CO) 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/08/2010, OBSERVADAS AS CONDICOES LEGAIS |
    优先权:
    申请号 | 申请日 | 专利标题
    US23690709P| true| 2009-08-26|2009-08-26|
    PCT/US2010/046754|WO2011025858A1|2009-08-26|2010-08-26|Printed flexible film for food packaging|
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